profile_path="\\fileserver.net\Common\network\Wireless Network Connection-home-network.xml"

import os
import ctypes
class disable_file_system_redirection:
    _disable = ctypes.windll.kernel32.Wow64DisableWow64FsRedirection
    _revert = ctypes.windll.kernel32.Wow64RevertWow64FsRedirection
    def __enter__(self):
        self.old_value = ctypes.c_long()
        self.success = self._disable(ctypes.byref(self.old_value))
    def __exit__(self, type, value, traceback):
        if self.success:
            self._revert(self.old_value)

with disable_file_system_redirection():    
    print os.popen('netsh wlan add profile filename="'+profile_path+'" user=all').read()
    print os.popen('netsh wlan show profiles').read()